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dissociative adsorption. 173 Since direct interconversion between 25a and 25b is not possible, the rc-allyl intermediate alone cannot account for cis-trans isomerization, but only in combination with double-bond migration. 172 ,174 In contrast with the Horiuti-Polanyi mechanism, isomerization and hydrogen addition are separate processes in the dissociative mechanism. Metals differ in their ability to catalyze isomerizations. Both the relative rates of isomerization of individual alkenes and the initial isomer distribution vary with the metal. The rates of isomerization of the three n-butenes on ruthenium and osmium, for example, are cis-2- > trans-2- > I-butene,175 whereas on platinum and iridium they are cis-2- > 1- > trans-2-butene. 176 These observations are in accordance with the fact that the rates of formation of the 1- and 2-butyl intermediates are different on the different metals. The order of decreasing activity of platinum metals in catalyzing the isomerization of dimethylcyclohexenes was found to be Pd Rh,

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Figure 22-1: The Go To Detail Page server behavior within the Repeat Region connects the master page to the proper detail page.

<s:Application xmlns:fx= http://ns.adobe.com/mxml/2009 xmlns:s= library://ns.adobe.com/flex/spark xmlns:mx= library://ns.adobe.com/flex/mx xmlns:components= components.* >

Use the Eyedropper Tool to acquire text: Click extant text to acquire all of the formatting and attributes and apply these settings to subsequently entered text. If your handling of text demands a more robust and thorough environment, you can generate your text in Freehand (or Illustrator) and import that more refined text into Flash. For more information on this type workflow, refer to 31, Working with Vector Graphics.

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Foremost among online forums for all things FileMaker is FMForums.com, boasting more than 40,000 members and approaching a decade online. The largest single online community of FileMaker users and developers, FMForums attracts a diverse group of participants representing all levels from the merest of beginners to the most accomplished professionals. Also worthy of mention is the RealTech list operated for members of FMPug and dealing with a broad range of technical issues and challenges relating to FileMaker and FileMaker-related products and solutions. In addition, a number of the user groups listed on the FMPug site sponsor their own mailing lists, wiki Web sites, or online resource pages.

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With respect to oligonucleotides-/oligodeoxynucleotides, the parent molecular ion may be identi ed by most MALDI and ESI mass spectrometry In addition, besides detection of the molecular ion, primary structure information can be gained from studying the mass spectra of an individual oligonucleotide-/oligodeoxynucleotide as with oligo-/polypeptides With regard to ESI mass spectrometry, negative ion mode tends to give better results than positive ion mode, yielding a sequence of multiply charged molecular ions [M zH]z Metal cation must be excluded from oligonucleotide-/oligodeoxynucleotide samples, since metal cation adducts suppress signal to noise and complicate spectra By contrast, MALDI mass spectrometry has proved more useful for primary structure analysis Once again, it is important to take steps to avoid metal cation adduct formation The recommended matrix when working with oligonucleotides-/oligodeoxynucleotides is hydroxypinolic acid (HPA).

These modifications are incorporated into the animated graph in the next subsection. 12.4.3 Animated object When an object changes its location gradually in each scan, it creates the illusion of motion and becomes animated. To achieve this, we can use registers to store the boundaries of an object and update its value in each scan. In the pong game, the paddle is controlled by two pushbuttons and can move up and down, and the ball can move and bounce in all directions. We illustrate how to create animation for these two objects in this subsection. While the VGA controller is driven by a 25-MHz pixel rate, the screen of the VGA monitor is refreshed only 60 times per second. The boundary registers only need to be updated at this rate. We create a 60-Hz enable tick, r e f r - t i c k , which is asserted one clock second. cycle every Let us first examine the design of the paddle. To accommodate the changing y-axis coordinates, we replace the constants with two signals, bar-y-t and bar-y-b, to represent the top and bottom boundaries, and create a register, bar-y-reg, to store the current yaxis location of the top boundary. If one of the pushbuttons is pressed, bar-y-reg either increases or decreases a fixed amount when the r e f r - t i c k signal is asserted. The amount is defined by a constant, BAR-V, which stands for the bar velocity. We assume that assertion of the b t n ( 1 ) and b t n ( 0 ) signals causes the paddle to move up and down, respectively, and that the paddle stops moving when it reaches the top or the bottom of the screen. The code segment for updating bar-y-reg is

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